Unique Three-dimensionally Expanded Nanoporous Structure Constructed with a Cu(I) and cis,cis-1,3,5-Triaminocyclohexane Having a 3-Fold Axial Symmetry

Unique Three-dimensionally Expanded Nanoporous Structure Constructed with a Cu(I) and cis,cis-1,3,5-Triaminocyclohexane Having a 3-Fold Axial Symmetry

Unique supramolecular crystal with a large macrocyclic channel structure has been prepared from the reaction of a [CuI(MeCN)4]SbF6 and cis,cis-1,3,5-triaminocyclohexane with a three-fold axial symmetry, whose channel is constructed from a distorted pseudofive-fold axial symmetric ring with a pore si...

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Veröffentlicht in:Chemistry letters 2003-01, Vol.32 (1), p.106-107
Hauptverfasser: Arii, Hidekazu, Saito, Yamato, Funahashi, Yasuhiro, Jitsukawa, Koichiro, Masuda, Hideki
Format: Artikel
Sprache:eng
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Zusammenfassung:Unique supramolecular crystal with a large macrocyclic channel structure has been prepared from the reaction of a [CuI(MeCN)4]SbF6 and cis,cis-1,3,5-triaminocyclohexane with a three-fold axial symmetry, whose channel is constructed from a distorted pseudofive-fold axial symmetric ring with a pore size of 5×12 Å2.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2003.106