Domino Oxidation of Ladder Oligosilanes: Formation of Novel Ladder Frameworks Containing Oligosiloxane and Oligosilane Chains
The domino oxidation predominates in the tri-, tetra-, and penta-oxidations of tricyclic, tetracyclic, and pentacyclic ladder oligosilanes 5, 7, and 9 with m-chloroperoxybenzoic acid. The structures of these products were determined by X-ray crystallography. The resulting domino oxidation products 6...
Gespeichert in:
| Veröffentlicht in: | Chemistry letters 1999-12, Vol.28 (12), p.1297-1298 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The domino oxidation predominates in the tri-, tetra-, and penta-oxidations of tricyclic, tetracyclic, and pentacyclic ladder oligosilanes 5, 7, and 9 with m-chloroperoxybenzoic acid. The structures of these products were determined by X-ray crystallography. The resulting domino oxidation products 6, 8, and 10 show intense absorption bands in the UV spectra. |
|---|---|
| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.1999.1297 |