Cycloreductions via Alkylpalladium Intermediates: Substrate Dependent Cyclopropanations of Palladium Catalyzed Enediyne Cyclizations

Cycloreductions via Alkylpalladium Intermediates: Substrate Dependent Cyclopropanations of Palladium Catalyzed Enediyne Cyclizations

We have found for the first time that enediynes possessing an etheral oxygen in the appropriate position have been successfully cyclized via the alkylpalladium intermediates to the corresponding cyclopropane compounds.

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Veröffentlicht in:Chemistry letters 1998-04, Vol.27 (4), p.375-376
Hauptverfasser: Oh, Chang Ho, Kang, Ji Hye, Rhim, Chul Yun, Kim, Ji Hyang
Format: Artikel
Sprache:eng
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Zusammenfassung:We have found for the first time that enediynes possessing an etheral oxygen in the appropriate position have been successfully cyclized via the alkylpalladium intermediates to the corresponding cyclopropane compounds.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1998.375