First Synthesis and Structure of Hexavalent Organic σ-Perselenurane Species (λ6-Selane): Bis(2,2′-biphenylylene)difluoroperselenurane [12-Se-6(C4F2)]

First Synthesis and Structure of Hexavalent Organic σ-Perselenurane Species (λ6-Selane): Bis(2,2′-biphenylylene)difluoroperselenurane [12-Se-6(C4F2)]

Bis(2,2′-biphenylylene)selenurane (1; λ4-selane) reacts with xenon difluoride to give bis(2,2′-biphenylylene)difluoroperselenurane, [12-Se-6(C4F2)] (2; λ6-selane), which was analyzed by single crystal X-ray diffraction.

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Veröffentlicht in:Chemistry letters 1998-03, Vol.27 (3), p.213-214
Hauptverfasser: Sato, Soichi, Arakawa, Hiroshi, Horn, Ernst, Furukawa, Naomichi
Format: Artikel
Sprache:eng
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Zusammenfassung:Bis(2,2′-biphenylylene)selenurane (1; λ4-selane) reacts with xenon difluoride to give bis(2,2′-biphenylylene)difluoroperselenurane, [12-Se-6(C4F2)] (2; λ6-selane), which was analyzed by single crystal X-ray diffraction.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1998.213