The First Example of μ-Oxo-bis(μ-carboxylato)dioxovanadium(IV,V) Complex

A novel dinuclear oxovanadium(IV,V) complex, [(VO)2(O)(Ph2CHCOO)2(bpy)2]NO3·CH3OH (1), has been prepared. X-Ray structural analysis has revealed that 1 has a μ-oxo-bis(μ-carboxylato)-bridged structure. Magnetic susceptibility data for 1 show the paramagnetic behavior which is attributable to the d1-...

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Veröffentlicht in:	Chemistry letters 1997-01, Vol.26 (5), p.463-464
Hauptverfasser:	Fukuda, Izumi, Matsushima, Hideaki, Maeda, Kouichi, Koikawa, Masayuki, Tokii, Tadashi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A novel dinuclear oxovanadium(IV,V) complex, [(VO)2(O)(Ph2CHCOO)2(bpy)2]NO3·CH3OH (1), has been prepared. X-Ray structural analysis has revealed that 1 has a μ-oxo-bis(μ-carboxylato)-bridged structure. Magnetic susceptibility data for 1 show the paramagnetic behavior which is attributable to the d1-d0 system.
ISSN:	0366-7022 1348-0715
DOI:	10.1246/cl.1997.463