Asymmetric Intramolecular C-H/Olefin Coupling: Asymmetric Cyclization Reactions of 1,5-Dienes Catalyzed by Rhodium Complexes

Asymmetric Intramolecular C-H/Olefin Coupling: Asymmetric Cyclization Reactions of 1,5-Dienes Catalyzed by Rhodium Complexes

Asymmetric intramolecular C-H/olefin coupling reactions of 1-(2-pyridyl)- or 1-(1- methyl-2-imidazolyl)-1,5-dienes are catalyzed by a rhodium complex having a homochiral monodentate phosphine ligand.

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Veröffentlicht in:Chemistry letters 1997-05, Vol.26 (5), p.425-426
Hauptverfasser: Fujii, Naoaki, Kakiuchi, Fumitoshi, Yamada, Airi, Chatani, Naoto, Murai, Shinji
Format: Artikel
Sprache:eng
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Zusammenfassung:Asymmetric intramolecular C-H/olefin coupling reactions of 1-(2-pyridyl)- or 1-(1- methyl-2-imidazolyl)-1,5-dienes are catalyzed by a rhodium complex having a homochiral monodentate phosphine ligand.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1997.425