Remote Oxygen Migration Reaction between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate

Remote Oxygen Migration Reaction between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate

The oxygen migration reaction between sulfur atoms in the monooxide of 1,4-bis(methylthio)benzene preceeds in the presence of CF3CO2H. The reaction of 1,4-bis(methylthio)benzene with its bis-sulfoxide also gives the corresponding monooxide at room temperature. A two-point bis(dithia dication) dimer...

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Veröffentlicht in:Chemistry letters 1997-11, Vol.26 (11), p.1175-1176
Hauptverfasser: Kobayashi, Kenji, Obinata, Takanobu, Furukawa, Naomichi
Format: Artikel
Sprache:eng
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Zusammenfassung:The oxygen migration reaction between sulfur atoms in the monooxide of 1,4-bis(methylthio)benzene preceeds in the presence of CF3CO2H. The reaction of 1,4-bis(methylthio)benzene with its bis-sulfoxide also gives the corresponding monooxide at room temperature. A two-point bis(dithia dication) dimer is proposed as an intermediate.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1997.1175