Preparation of a Polymer with Limited π-Conjugation Length: A Polymer Containing Quaterthiophene Units

A polymer containing quaterthiophene units in the main chain was prepared by electrochemical polymerization of 1,2-bis(3′-hexyl-2,2′-bithiophene-5-yl)ethane. The obtained green film had a conductivity of 2 × 10−2 S cm−1 in oxidized states and was neutralized by immersing in methanol. The cyclic volt...

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Veröffentlicht in:Chemistry letters 1996-06, Vol.25 (6), p.495-496
Hauptverfasser: Sato, Masa-aki, Hiroi, Masao
Format: Artikel
Sprache:eng
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Zusammenfassung:A polymer containing quaterthiophene units in the main chain was prepared by electrochemical polymerization of 1,2-bis(3′-hexyl-2,2′-bithiophene-5-yl)ethane. The obtained green film had a conductivity of 2 × 10−2 S cm−1 in oxidized states and was neutralized by immersing in methanol. The cyclic voltammograms of the neutral film showed only an oxidation process in the first cycle.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1996.495