Enantioselective Recognition of [60]Fullerene Bisadducts by Cyclodextrin: Kinetic Control of a Mechanochemical High-speed Vibration Milling Process

Enantioselective Recognition of [60]Fullerene Bisadducts by Cyclodextrin: Kinetic Control of a Mechanochemical High-speed Vibration Milling Process

The enantiomers of some fullerene bisadducts were separated by complexation with γ-cyclodextrin (γ-CDx) in a mechanochemical high-speed vibration milling (HSVM) apparatus, followed by decomplexation with the addition of DMSO. HSVM treatment, which is generally used for pharmaceutical preparation, wa...

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Veröffentlicht in:Chemistry letters 2013, Vol.42 (10), p.1137-1139
Hauptverfasser: Ikeda, Atsushi, Ishikawa, Michiko, Kikuchi, Jun-ichi, Nobusawa, Kazuyuki
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container_title Chemistry letters
container_volume 42
creator Ikeda, Atsushi
Ishikawa, Michiko
Kikuchi, Jun-ichi
Nobusawa, Kazuyuki
description The enantiomers of some fullerene bisadducts were separated by complexation with γ-cyclodextrin (γ-CDx) in a mechanochemical high-speed vibration milling (HSVM) apparatus, followed by decomplexation with the addition of DMSO. HSVM treatment, which is generally used for pharmaceutical preparation, was found to be governed not by thermodynamic control but by kinetic control.
doi_str_mv 10.1246/cl.130515
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source Oxford University Press Journals All Titles (1996-Current)
title Enantioselective Recognition of [60]Fullerene Bisadducts by Cyclodextrin: Kinetic Control of a Mechanochemical High-speed Vibration Milling Process
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