Enantioselective Recognition of [60]Fullerene Bisadducts by Cyclodextrin: Kinetic Control of a Mechanochemical High-speed Vibration Milling Process

Enantioselective Recognition of [60]Fullerene Bisadducts by Cyclodextrin: Kinetic Control of a Mechanochemical High-speed Vibration Milling Process

The enantiomers of some fullerene bisadducts were separated by complexation with γ-cyclodextrin (γ-CDx) in a mechanochemical high-speed vibration milling (HSVM) apparatus, followed by decomplexation with the addition of DMSO. HSVM treatment, which is generally used for pharmaceutical preparation, wa...

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Veröffentlicht in:Chemistry letters 2013, Vol.42 (10), p.1137-1139
Hauptverfasser: Ikeda, Atsushi, Ishikawa, Michiko, Kikuchi, Jun-ichi, Nobusawa, Kazuyuki
Format: Artikel
Sprache:eng
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Zusammenfassung:The enantiomers of some fullerene bisadducts were separated by complexation with γ-cyclodextrin (γ-CDx) in a mechanochemical high-speed vibration milling (HSVM) apparatus, followed by decomplexation with the addition of DMSO. HSVM treatment, which is generally used for pharmaceutical preparation, was found to be governed not by thermodynamic control but by kinetic control.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.130515