A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: Tetramethylethylenediamine, azpy: 4,4′-Azopyridine)
A novel triangle-shaped macrocyclic complex, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: tetramethylethylenediamine, azpy: 4,4′-azopyridine) has been successfully synthesized via self-assembly of [(tmeda)PtCl2] with a bulky capping ligand, tmeda and flexible organic linker, azpy. 1H NMR results show the...
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Veröffentlicht in: | Chemistry letters 2013-04, Vol.42 (4), p.374-376 |
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container_title | Chemistry letters |
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creator | Hashiguchi, Ryota Otsubo, Kazuya Ohtsu, Hideki Kitagawa, Hiroshi |
description | A novel triangle-shaped macrocyclic complex, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: tetramethylethylenediamine, azpy: 4,4′-azopyridine) has been successfully synthesized via self-assembly of [(tmeda)PtCl2] with a bulky capping ligand, tmeda and flexible organic linker, azpy. 1H NMR results show the realization of a triangle-shaped complex as a major component of the self-assembly. The single-crystal X-ray study shows its shape to be an equilateral triangle with ca. 2.1 nm sides. |
doi_str_mv | 10.1246/cl.121240 |
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The single-crystal X-ray study shows its shape to be an equilateral triangle with ca. 2.1 nm sides.</abstract><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.121240</doi><tpages>3</tpages></addata></record> |
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source | Oxford University Press Journals All Titles (1996-Current) |
title | A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: Tetramethylethylenediamine, azpy: 4,4′-Azopyridine) |
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