A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: Tetramethylethylenediamine, azpy: 4,4′-Azopyridine)

A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: Tetramethylethylenediamine, azpy: 4,4′-Azopyridine)

A novel triangle-shaped macrocyclic complex, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: tetramethylethylenediamine, azpy: 4,4′-azopyridine) has been successfully synthesized via self-assembly of [(tmeda)PtCl2] with a bulky capping ligand, tmeda and flexible organic linker, azpy. 1H NMR results show the...

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Veröffentlicht in:Chemistry letters 2013-04, Vol.42 (4), p.374-376
Hauptverfasser: Hashiguchi, Ryota, Otsubo, Kazuya, Ohtsu, Hideki, Kitagawa, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel triangle-shaped macrocyclic complex, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: tetramethylethylenediamine, azpy: 4,4′-azopyridine) has been successfully synthesized via self-assembly of [(tmeda)PtCl2] with a bulky capping ligand, tmeda and flexible organic linker, azpy. 1H NMR results show the realization of a triangle-shaped complex as a major component of the self-assembly. The single-crystal X-ray study shows its shape to be an equilateral triangle with ca. 2.1 nm sides.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.121240