Mapping the glassy dynamics of soft spheres onto hard-sphere behavior

We show that the dynamics of soft-sphere systems with purely repulsive interactions can be described by introducing an effective hard-sphere diameter determined using the Andersen-Weeks-Chandler approximation. We find that this approximation, known to describe static properties of liquids, also give...

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Veröffentlicht in:Europhysics letters 2011-11, Vol.96 (3), p.36010
Hauptverfasser: Schmiedeberg, M, Haxton, T. K, Nagel, S. R, Liu, A. J
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Sprache:eng
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Zusammenfassung:We show that the dynamics of soft-sphere systems with purely repulsive interactions can be described by introducing an effective hard-sphere diameter determined using the Andersen-Weeks-Chandler approximation. We find that this approximation, known to describe static properties of liquids, also gives a good description of a dynamical quantity, the relaxation time, even in the vicinity of the glass transition.
ISSN:0295-5075
1286-4854
DOI:10.1209/0295-5075/96/36010