Hybrid PP-EPR-GF composites. Part II: fracture mechanisms

The fracture mechanism of hybrid iPP-EPR-GF composites has been studied by notched Charpy, three- and four-point bending fracture tests. The results of impact tests illustrate that increasing both temperature and EPR/GF ratio increases the impact energy of iPP-EPR-GF. Indeed, with increasing temperature, a brittle, ductile, transition temperature (BDTT) occurs. The results of a three-point bending test show that fracture toughness (K IC ) can be improved by addition of both GF and EPR. Since the trend in the fracture toughness values is close to what would be expected by the rule of blends, it can be concluded that the use of both GF and EPR has no significant synergistic effect on toughening. The results of a four-point bending test show that craze-like damage appears in front of the pre-crack and its propagation is dictated by the GF and EPR content. Looking in more detail at the damaged zone by means of cross-polarised light microscopy, evidence of birefringence can be revealed. Briefly, the dominant mechanism of fracture in the iPP-EPR-GF system studied in this work can be related to a craze-like type damage, which includes both highly localised dilatational shear bands, due to cavitation of the EPR particles, and some crazing induced by the stress concentration associated with GF.