Asymmetric Synthesis of Tetrahydroisoquinoline Alkaloids Using Ellman's Chiral Auxiliary

Asymmetric Synthesis of Tetrahydroisoquinoline Alkaloids Using Ellman's Chiral Auxiliary

Chiral t-butylsulfinamide has been successfully employed for the stereoselective synthesis of 1-benzyl tetrahydroisoquinoline alkaloids. This is the first report on the synthesis of chiral 1-benzyltetrahydroisoquinoline natural products using tert-butylsulfinamide through a haloamide cyclization.

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Veröffentlicht in:Natural product communications 2017-10, Vol.12 (10)
Hauptverfasser: Reddy, Y. Vikram, Biradar, Dhanraj O., Reddy, B. Jagan Mohan, Rathod, Aravinda, Himabindu, M., Reddya, B. V. Subba
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container_issue 10
container_start_page
container_title Natural product communications
container_volume 12
creator Reddy, Y. Vikram
Biradar, Dhanraj O.
Reddy, B. Jagan Mohan
Rathod, Aravinda
Himabindu, M.
Reddya, B. V. Subba
description Chiral t-butylsulfinamide has been successfully employed for the stereoselective synthesis of 1-benzyl tetrahydroisoquinoline alkaloids. This is the first report on the synthesis of chiral 1-benzyltetrahydroisoquinoline natural products using tert-butylsulfinamide through a haloamide cyclization.
doi_str_mv 10.1177/1934578X1701201019
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title Asymmetric Synthesis of Tetrahydroisoquinoline Alkaloids Using Ellman's Chiral Auxiliary
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