Vinyltriphenylphosphonium Salt-mediated New Synthesis of Functionalized Maleimides

Vinyltriphenylphosphonium Salt-mediated New Synthesis of Functionalized Maleimides

N-Methyl-2-chloroacetoacetamide undergoes a complex reaction with dialkyl acetylenedicarboxylates and triphenylphosphine to produce dialkyl 2-( N-methyl-2-chloroacetoacetamide-2-yl)-3-(triphenylphosphoranylidene)-butanedioates, which undergo elimination-cyclization reactions to produce N-methyl-4-ac...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical research 1999-03, Vol.23 (3), p.234-235
Hauptverfasser: Yavari, Issa, Asghari, Sakineh, Esmaili, Abbas Ali
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:N-Methyl-2-chloroacetoacetamide undergoes a complex reaction with dialkyl acetylenedicarboxylates and triphenylphosphine to produce dialkyl 2-( N-methyl-2-chloroacetoacetamide-2-yl)-3-(triphenylphosphoranylidene)-butanedioates, which undergo elimination-cyclization reactions to produce N-methyl-4-acetyl-3-(alkoxycarbonyltriphenylphosphoranylidene)-maleimides.
ISSN:1747-5198
2047-6507
DOI:10.1177/174751989902300332