Sodium Periodate Epoxidation of Alkenes Catalysed by Manganese Porphyrins

Sodium Periodate Epoxidation of Alkenes Catalysed by Manganese Porphyrins

Epoxidation of alkenes with different electronic and steric properties has been performed with high selectivity by sodium periodate in the presence of acetatotetraarylporphinatomanganese(III) complexes containing electron releasing or withdrawing groups at the ortho positions of the aryl rings, in a...

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Veröffentlicht in:Journal of chemical research 1999-02, Vol.23 (2), p.168-169
Hauptverfasser: Mohajer, Daryoush, Tayebee, Reza, Goudarziafshar, Hameed
Format: Artikel
Sprache:eng
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Zusammenfassung:Epoxidation of alkenes with different electronic and steric properties has been performed with high selectivity by sodium periodate in the presence of acetatotetraarylporphinatomanganese(III) complexes containing electron releasing or withdrawing groups at the ortho positions of the aryl rings, in a two-phase (CH 2 CI 2 –H 2 O) medium at 24 ± 2 °C.
ISSN:1747-5198
2047-6507
DOI:10.1177/174751989902300251