A ruthenium nanocatalyst for the atmospheric hydrogenation of 1,5-cyclooctadiene
A ruthenium nanocatalyst is utilized for the first time for the highly efficient and selective hydrogenation of 1,5-cyclooctadiene under atmospheric hydrogen pressure. Under the optimized reaction conditions, the conversion of 1,5-cyclooctadiene and the selectivity for cyclooctene are >99% and 95...
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| Veröffentlicht in: | Journal of chemical research 2022-03, Vol.46 (2) |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A ruthenium nanocatalyst is utilized for the first time for the highly efficient and selective hydrogenation of 1,5-cyclooctadiene under atmospheric hydrogen pressure. Under the optimized reaction conditions, the conversion of 1,5-cyclooctadiene and the selectivity for cyclooctene are >99% and 95%, respectively. The turnover frequency is 451 h−1, which is higher than that ever reported for Ru complex catalysts. |
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| ISSN: | 1747-5198 2047-6507 |
| DOI: | 10.1177/17475198221092945 |