Fabrication of biopolyethylene-based biocomposites with coffee ground waste: Effect of polyethylene-graft-maleic anhydride
The production of plastic products from non-renewable raw materials, such as petroleum, damages the environment. Consequently, biocomposites have aroused interest from industry and researchers due to their ecologically correct characteristics, mainly because they come from renewable sources. Therefo...
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Veröffentlicht in: | Journal of composite materials 2024-08, Vol.58 (20), p.2313-2324 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The production of plastic products from non-renewable raw materials, such as petroleum, damages the environment. Consequently, biocomposites have aroused interest from industry and researchers due to their ecologically correct characteristics, mainly because they come from renewable sources. Therefore, this study aimed to produce biopolyethylene/coffee ground waste (BioPE/CGW) biocomposites and analyze the impact of CGW and polyethylene-graft-maleic anhydride (PE-g-MA) on BioPE. The biocomposites were prepared in a co-rotational twin-screw extruder equipped with a side feeder to feed the CGW. The materials were subsequently injection molded to produce the impact, tensile, and HDT samples. The temperature profiles used during extrusion and injection were between 170 and 180°C. The BioPE and biocomposites were investigated for the vibrational (Infrared Spectroscopy - FTIR), thermal (differential scanning calorimetry), mechanical (tensile, impact, and hardness), thermomechanical (heat deflection temperature (HDT) and Vicat softening temperature (VST)), and morphological (scanning electron microscopy (SEM)) properties. The compatibilizer improved the interface between phases, promoting mechanical and thermomechanical improvements in the biocomposites. PE-g-MA promoted increments in tensile strength and elastic modulus of up to 38% and 25% in the BioPE/CGW30 and an increase of 44% in the elastic modulus compared to BioPE. The thermomechanical investigations showed that HDT increased by 8.8 and 3.3°C and VST increased by 2.5 and 6.6°C compared to BioPE and the BioPE/CGW30, respectively. Biocomposites from renewable and biodegradable sources align with a sustainable development concept. |
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ISSN: | 0021-9983 1530-793X |
DOI: | 10.1177/00219983241264057 |