Transient Absorption and RamanStudies on Exciplex FormationDynamics of PhotoexcitedCu(II)(TMpy‐P4) With SyntheticPolynucleotide
Exciplex formation dynamics of photoexcited copper(II) tetrakis (4‐ N ‐methylpyridyl) porphyrin (Cu(II)(TMpy‐P4)) with added poly(dA‐dT) 2 and poly(dG‐dC) 2 has been investigated by using femtosecond transient absorption and nanosecond and picosecond transient Raman spectroscopic methods. It was obs...
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| Veröffentlicht in: | Laser chemistry 1999-01, Vol.19 (1-4), p.299-303 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Exciplex formation dynamics of photoexcited copper(II) tetrakis (4‐
N
‐methylpyridyl)
porphyrin (Cu(II)(TMpy‐P4)) with added poly(dA‐dT)
2
and poly(dG‐dC)
2
has been
investigated by using femtosecond transient absorption and nanosecond and picosecond
transient Raman spectroscopic methods. It was observed that the decay time constant of
the exciplex is strongly dependent on the polynucleotide and has a strong correlation
with the appearance of new transient Raman bands. |
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| ISSN: | 0278-6273 1476-3516 |
| DOI: | 10.1155/1999/52027 |