Long-Term Cycling Stability of 18650 Li-Ion Batteries Cells Using NMC811 Core@Shell Structure with Tetra-Materials

LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) material has been considered as a next-generation cathode of lithium-ion batteries, which can be used for many applications such as long-distance electric vehicles. Although NMC811 has high theoretical specific capacity and energy, its major drawbacks such as micr...

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Veröffentlicht in:Meeting abstracts (Electrochemical Society) 2021-05, Vol.MA2021-01 (4), p.246-246
Hauptverfasser: Khunrugsa, Chirayu, Chiochan, Poramane, Duriyasart, Farkfun, Jangsan, Chonticha, Kullawattanapokin, Pattranit, Sawangphruk, Montree
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Sprache:eng
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Zusammenfassung:LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) material has been considered as a next-generation cathode of lithium-ion batteries, which can be used for many applications such as long-distance electric vehicles. Although NMC811 has high theoretical specific capacity and energy, its major drawbacks such as microcracks, cation mixing, too reactive surface reaction, result in poor long-term cycling and stability. In this work, the tetra-materials of garnet (Li 7 La 3 Zr 2 O 12 ), reduced graphene oxide (rGO), carbon black (CB), and titanium dioxide (TiO 2 ) were coated on the surface of the NMC particle by a green and scalable mechano-fusion technique, forming the core@shell structure (namely NMC@4M) to protect the morphological instability and the electrolyte decomposition leading to long-term cycling stability. Also, the 4M shell elevates the Li-ion diffusion and ionic conductivity. Moreover, we have firstly reported the finely tuned step formation protocol of cylindrical cell type in lithium-ion battery (18650). As a result, the NMC@4T can deliver high-capacity retention over 85% after long cycling (400 cycles) at 1C. Figure 1
ISSN:2151-2043
2151-2035
DOI:10.1149/MA2021-014246mtgabs