High-Efficiency Red-Emitting Phosphor of Li 0.5 La 0.5 SrMgWO 6 : Mn 4+ , Pr 3

The 400–500 nm blue light and 630–750 nm red light play crucial roles in plant cultivation. In this work, a high efficiency red-emitting phosphor, Li 0.5 La 0.5 SrMgWO 6 :Mn 4+ , Pr 3+ , was synthesized through the solid-state reaction technique. The absorption and excitation spectra were measured,...

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Veröffentlicht in:ECS journal of solid state science and technology 2023-11, Vol.12 (11), p.116003
Hauptverfasser: Hu, Shaozu, Yang, Fugui, Yan, Fengpo, Yu, Yunlong, Wu, Yonghua
Format: Artikel
Sprache:eng
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Zusammenfassung:The 400–500 nm blue light and 630–750 nm red light play crucial roles in plant cultivation. In this work, a high efficiency red-emitting phosphor, Li 0.5 La 0.5 SrMgWO 6 :Mn 4+ , Pr 3+ , was synthesized through the solid-state reaction technique. The absorption and excitation spectra were measured, indicating that 467 nm was an suitable excitation wavelength for this material. Upon excitation with a 467 nm LED, the fluorescence characteristics were evaluated, revealing dual-band red emission peaks located at 621–654 nm and 695–710 nm. The quantum efficiency and pumping slope efficiency were measured to be 63% and 35%, respectively. Based on energy level theory and Tanabe-Sugano theory, the dual-band fluorescence mechanism was analyzed, revealing that cross relaxation phenomenon contributed to the high quantum efficiency. The temperature sensing property was also demonstrated. The relative sensitivity (Sr) exhibited a significant change from 0.05% K −1 to 0.85% K −1 with different temperatures. The phosphor’s high efficiency and exceptional temperature property confer it with extensive potential applications in the fields of plant cultivation and display technology.
ISSN:2162-8769
2162-8777
DOI:10.1149/2162-8777/ad0aaf