DyScHfOx as High-κ Gate Dielectrics: Structural and Electrical Properties
DyScHfOx high-κ dielectric thin films have been grown by atomic vapor deposition using Dy(EDMDD)3, Sc(EDMDD)3, and Hf(OBut)2(mmp)2. It was found that the entire DyxScyHfzOw com-positional range can be realized with this process. XRD showed that DyScO3 was amorphous as grown, whereas ScHfOx and Dy-Hf...
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Veröffentlicht in: | ECS transactions 2007-04, Vol.6 (1), p.113-120 |
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creator | Adelmann, Christoph Van Elshocht, Sven Lehnen, Peer Conard, Thierry Franquet, Alexis Zhao, Chao Ragnarsson, Lars-Ake Chang, Vincent Cho, Hag-Ju Hong-Yu, Yu De Gendt, Stefan |
description | DyScHfOx high-κ dielectric thin films have been grown by atomic vapor deposition using Dy(EDMDD)3, Sc(EDMDD)3, and Hf(OBut)2(mmp)2. It was found that the entire DyxScyHfzOw com-positional range can be realized with this process. XRD showed that DyScO3 was amorphous as grown, whereas ScHfOx and Dy-HfOx were crystalline. The crystalline phase of both HfxSc1-xOy and HfxDy1-xOy changed from monoclinic to cubic around x = 0.1. Electrical characterization of nMOS capacitors and long-channel transistors showed that the EOT-leakage scaling of DyScOx was comparable to that of HfO2, whereas both DyHfOx and ScHfOx were comparable to HfSiO4. For the DyScHfOx materials, the elec-tron mobility was improved with respect to devices with HfO2 as a gate dielectric. |
doi_str_mv | 10.1149/1.2727394 |
format | Article |
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It was found that the entire DyxScyHfzOw com-positional range can be realized with this process. XRD showed that DyScO3 was amorphous as grown, whereas ScHfOx and Dy-HfOx were crystalline. The crystalline phase of both HfxSc1-xOy and HfxDy1-xOy changed from monoclinic to cubic around x = 0.1. Electrical characterization of nMOS capacitors and long-channel transistors showed that the EOT-leakage scaling of DyScOx was comparable to that of HfO2, whereas both DyHfOx and ScHfOx were comparable to HfSiO4. For the DyScHfOx materials, the elec-tron mobility was improved with respect to devices with HfO2 as a gate dielectric.</abstract><doi>10.1149/1.2727394</doi></addata></record> |
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title | DyScHfOx as High-κ Gate Dielectrics: Structural and Electrical Properties |
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