The Kinetics of the Self‐Discharge Reaction in a Sealed Lead‐Acid Cell

The Kinetics of the Self‐Discharge Reaction in a Sealed Lead‐Acid Cell

The kinetics and mechanism of the self-discharge reaction in a sealed, lead--acid cell were investigated. The unique cell design and the purity of the materials used produce a slower rate of self-discharge and a different mechanism than the traditional lead--acid battery. Particular attention is giv...

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Veröffentlicht in:J. Electrochem. Soc.; (United States) 1976-03, Vol.123 (3), p.327-331
Hauptverfasser: Bullock, Kathryn R., McClelland, Donald H.
Format: Artikel
Sprache:eng
Schlagworte:
250902 - Energy Storage- Batteries- Performance & Testing
ADDITIVES
ANODES
CHEMICAL REACTION KINETICS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
ENERGY STORAGE
ENERGY STORAGE SYSTEMS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
LEAD-ACID BATTERIES
MATERIALS
MEDIUM TEMPERATURE
PH VALUE
PHOSPHORIC ACID
REACTION KINETICS
SEALS
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Beschreibung
Zusammenfassung:The kinetics and mechanism of the self-discharge reaction in a sealed, lead--acid cell were investigated. The unique cell design and the purity of the materials used produce a slower rate of self-discharge and a different mechanism than the traditional lead--acid battery. Particular attention is given to the effects of expander composition and phosphoric acid concentration on the reaction. Rates of the reaction are determined for temperatures in the range of 35 to 65/sup 0/C.
ISSN:0013-4651
1945-7111
DOI:10.1149/1.2132819