Electrochemical fluorination of anthracene derivatives. II

The controlled potential electrolyses of anthracene(I), 9-methylanthracene(II), and 9-phenylanthracene(III) in acetonitrile solutions containing (CH/sub 3/)/sub 4/ NF.2HF led to the formation of fluoro derivatives in the 9- and 10-positions. Yields were limited by dimer formation. The products from...

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Veröffentlicht in:	J. Electrochem. Soc.; (United States) 1983-11, Vol.130 (11), p.2170-2172
Hauptverfasser:	CARPENTER, J. F, EKES, L. H, KING, P. F, MARIANI, H. A, ZADEH, M. M, ÓMALLEY, R. F, ROMAN, V. J
Format:	Artikel
Sprache:	eng
Schlagworte:	ACETONITRILE ANTHRACENE AROMATICS CATIONS CHARGED PARTICLES CHEMICAL REACTION YIELD CHEMICAL REACTIONS Chemistry CONDENSED AROMATICS Condensed benzenic and aromatic compounds DIMERS DISPERSIONS ELECTROLYSIS Exact sciences and technology FLUORIDES FLUORINATED AROMATIC HYDROCARBONS FLUORINATION FLUORINE COMPOUNDS HALIDES HALOGEN COMPOUNDS HALOGENATED AROMATIC HYDROCARBONS HALOGENATION HYDROCARBONS HYDROFLUORIC ACID HYDROGEN COMPOUNDS INORGANIC ACIDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS LYSIS MIXTURES NITRILES NITROGEN COMPOUNDS NITROGEN FLUORIDES Organic chemistry ORGANIC COMPOUNDS ORGANIC FLUORINE COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC NITROGEN COMPOUNDS Preparations and properties PROCESS SOLUTIONS REACTION INTERMEDIATES SOLUTIONS YIELDS 400400 > Electrochemistry
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Zusammenfassung:	The controlled potential electrolyses of anthracene(I), 9-methylanthracene(II), and 9-phenylanthracene(III) in acetonitrile solutions containing (CH/sub 3/)/sub 4/ NF.2HF led to the formation of fluoro derivatives in the 9- and 10-positions. Yields were limited by dimer formation. The products from the electrolyses are consistent with the involvement of radical cations as intermediates.
ISSN:	0013-4651 1945-7111
DOI:	10.1149/1.2119546