Effect of Different Binders on the Power Characteristics for Carbon Fluorides in Lithium Primary Batteries

This study demonstrates the effect of different binders on the power characteristics of carbon fluorides (CF x ) cathode material for power-type lithium primary batteries. Specifically, polymer binders, such as polyacrylic latex (LA133), poly(vinylidene fluoride) (PVDF) and carboxymethyl cellulose (...

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Veröffentlicht in:Journal of the Electrochemical Society 2024-12, Vol.171 (12), p.120534
Hauptverfasser: Liu, Wen, Ma, Sen, Yan, Tingfang, Wan, Bingxin, Ma, Shangde, Li, Yong, Pei, Haijuan, Guo, Rui, Wu, Chao, Xie, Jingying
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Sprache:eng
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Zusammenfassung:This study demonstrates the effect of different binders on the power characteristics of carbon fluorides (CF x ) cathode material for power-type lithium primary batteries. Specifically, polymer binders, such as polyacrylic latex (LA133), poly(vinylidene fluoride) (PVDF) and carboxymethyl cellulose (CMC) are utilized in the preparation of CF x composite electrodes. The selection of binders significantly influences the rate performance of Li/CF x batteries. Among the binders tested, the LA133 binder notably reduces the electrode resistance and interface impedance of the batteries compared to PVDF and CMC, resulting in outstanding rate performance at 1 C. Additionally, this study discusses the impact of binder chemistry on the overall performance of the batteries.
ISSN:0013-4651
1945-7111
DOI:10.1149/1945-7111/ad9fe6