Rotating Basket Cathode for High-Speed Electrolytic Reduction of TiO 2 in Molten CaCl 2 -CaO
A rotating basket cathode improved the TiO2-reduction efficiency by 6.5-fold and accelerated the electrolysis of molten CaCl2-CaO at 1173 K in an Ar atmosphere. Promoting dissolution of the CaO byproduct and mass transfer near the cathode was effective for TiO2 reduction and α-Ti deoxidation. The re...
Gespeichert in:
| Veröffentlicht in: | Journal of the Electrochemical Society 2024-11 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | A rotating basket cathode improved the TiO2-reduction efficiency by 6.5-fold and accelerated the electrolysis of molten CaCl2-CaO at 1173 K in an Ar atmosphere. Promoting dissolution of the CaO byproduct and mass transfer near the cathode was effective for TiO2 reduction and α-Ti deoxidation. The reduction efficiency can be predicted by optimizing the rotational speed and pulse rotation. |
|---|---|
| ISSN: | 0013-4651 1945-7111 |
| DOI: | 10.1149/1945-7111/ad95c0 |