Improving Nickel Diselenide Performance toward Oxygen Reduction Reaction with Ruthenium Incorporation and Heat Treatment

A small amount of ruthenium (Ru) was introduced into carbon supported nickel diselenide (NiSe 2 /C) through a simple microwave route to obtain Ru incorporated ternary catalyst Ru(NiSe 2 )/C. A comparative study was performed without and with the heat treatment to examine the crystal phases, microstr...

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Veröffentlicht in:Journal of the Electrochemical Society 2022-04, Vol.169 (4), p.44518
Hauptverfasser: Liu, Jiaqi, Shen, Junfei, Gong, Qing, Hu, Peng, Cheng, Xuan, Li, Hengyi
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Sprache:eng
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Zusammenfassung:A small amount of ruthenium (Ru) was introduced into carbon supported nickel diselenide (NiSe 2 /C) through a simple microwave route to obtain Ru incorporated ternary catalyst Ru(NiSe 2 )/C. A comparative study was performed without and with the heat treatment to examine the crystal phases, microstructures, electrocatalytic activities and stabilities toward oxygen reduction reaction (ORR) for binary NiSe 2 /C and ternary Ru(NiSe 2 )/C. The results revealed that the half-wave potential ( E 1/2 ) of the best performed Ru(NiSe 2 )/C-400 reached 0.64 V with the overall loss of 5.6% in E 1/2 after 1000 cycles in 0.1 mol·l −1 HClO 4 , showing the highly improved ORR activity and excellent stability as compared with those of the best performed NiSe 2 /C-350. When tested as a cathode catalyst in the H 2 /O 2 single cell at 65 °C and ambient pressure, the open circuit potential and the maximum power density approached 0.78 V and 132 mW·cm −2 , respectively. The achieved mass activity of 0.08 mA·( μ g Ru) −1 at 0.75 V was comparable to that of Ru(CoSe 2 )/C-400 (0.09 mA·( μ g Ru) −1 ). The simultaneous enhancement in the ORR activity and stability of Ru(NiSe 2 )/C in an acid electrolyte might be mainly contributed by a new stable (Ru, Ni)Se 2 like structure. Furthermore, selenium evaporation and grain growth could be effectively prevented during the heat treatment by Ru incorporation.
ISSN:0013-4651
1945-7111
DOI:10.1149/1945-7111/ac645c