Electrochemical Fluorination of (Arylthio)methyl Carboxylates and γ-Phenylthio-γ-butyrolactone Derivative

Electrochemical Fluorination of (Arylthio)methyl Carboxylates and γ-Phenylthio-γ-butyrolactone Derivative

Electrochemical fluorination of various (arylthio)methyl carboxylates was carried out in aprotic organic solvents containing poly(HF) salts to provide the corresponding O-fluoromethyl carboxylates in good to moderate yield. Electrochemical fluorination of a cyclic analogue, a gamma-phenylthio-gamma-...

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Veröffentlicht in:Journal of the Electrochemical Society 2021-06, Vol.168 (6), p.65502, Article 065502
Hauptverfasser: Ito, Satoshi, Kondo, Kaori, Ishii, Hideki, Inagi, Shinsuke, Fuchigami, Toshio
Format: Artikel
Sprache:eng
Schlagworte:
Anodic Fluorination
Electrochemistry
Electrosynthesis
Fluorinated Esters
Materials Science
Materials Science, Coatings & Films
Organic Electrochemistry
Physical Sciences
Science & Technology
Technology
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Zusammenfassung:Electrochemical fluorination of various (arylthio)methyl carboxylates was carried out in aprotic organic solvents containing poly(HF) salts to provide the corresponding O-fluoromethyl carboxylates in good to moderate yield. Electrochemical fluorination of a cyclic analogue, a gamma-phenylthio-gamma-butyrolactone derivative was also achieved under ultrasonication to give the corresponding 4-fluorinated product in moderate yield.
ISSN:0013-4651
1945-7111
DOI:10.1149/1945-7111/ac07c2