Cycling Characteristics of Tubular Liquid Antimony Anode Direct Carbon Fuel Cells Prepared by Atmospheric Plasma Spray

Liquid antimony anode solid oxide fuel cell (LAA-SOFC) is a promising technology for efficient conversion of solid carbon and hydrocarbon fuels. However, the operating process and the regeneration method of the fuel cells with LAAs are different from those with solid anodes and still need to be investigated. In the present research, a tubular LAA-SOFC unit was fabricated by atmospheric plasma spraying based on a stainless-steel support. The LAA-SOFC was cycled by a furnace control method and a “hot plug” method to simulate the normal start-stop and the anode/cell replacement processes, respectively. Scarce degradation was observed after the cycles with phase change, redox, and temperature variation, which demonstrated the robustness of the sprayed electrolyte to the anode changes. The air leakage and the floating ash retarded the recovery rate of the “hot plug” cycles, but have no influence on the degradation degree. The cycling characteristics in the present research proved the long-term operating feasibility of SOFC with LAA.