Effect of pH in the Electrochemical Response ofSnO 2 -Carbon Black Composites and its Use as Anodes
In this work is carried out electrochemical characterization of SnO 2 -Carbon Black composites in electrolytes systems with different pH by means of lineal sweep voltammetry and chronoamperometry. The electrochemical responses were compared with Pt and DSA (Ti/IrO 2 /SnO 2 /Sb 2 O 5 ) electrodes, co...
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Veröffentlicht in: | ECS transactions 2013-09, Vol.47 (1), p.83-96 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this work is carried out electrochemical characterization of SnO
2
-Carbon Black composites in electrolytes systems with different pH by means of lineal sweep voltammetry and chronoamperometry. The electrochemical responses were compared with Pt and DSA (Ti/IrO
2
/SnO
2
/Sb
2
O
5
) electrodes, considering them as well behavior electrodes for water oxidation reaction. This study allows us to identify that SnO
2
-nCFE electrode depresses the water oxidation potential, the reaction is catalyzed, and the SnO
2
-SCFE electrode extends the oxygen evolution potential. Consequently the electrodes were evaluated in 0.1M KHCO
3
/CO
2
with pH 6.8, and 0.1M KHCO
3
2% Reactive Blue dye, respectively. The assessment in these specific systems enables to evaluate their possible use as anodes. In a future work, the efficiency and cell potential will be reported in order to confirm the effective performance of these electrodes materials. |
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ISSN: | 1938-5862 1938-6737 |
DOI: | 10.1149/04701.0083ecst |