Electrodeposition of Thick SmCo Films: Influence of Current Density and Time Deposition

Electrodeposition of SmCo in aqueous solution has been studied using a Hull cell. Different concentrations of cobalt ion in the electrolyte, addition of supporting electrolyte and different deposition time have been tested. High samarium contents and thicknesses have been obtained: up to 50 % of Sm...

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Veröffentlicht in:ECS transactions 2013-02, Vol.45 (14), p.15-23
Hauptverfasser: Chouarbi, Katia, Woytazik, Marion, Dufour-Gergam, Elisabeth, Lefeuvre, Elie, Moulin, Johan
Format: Artikel
Sprache:eng
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Zusammenfassung:Electrodeposition of SmCo in aqueous solution has been studied using a Hull cell. Different concentrations of cobalt ion in the electrolyte, addition of supporting electrolyte and different deposition time have been tested. High samarium contents and thicknesses have been obtained: up to 50 % of Sm in the deposit and several microns. The oxygen contamination is linked to the samarium content and two elaboration parameters have been targeted for limiting this contamination: addition of supporting electrolyte and long deposition time.
ISSN:1938-5862
1938-6737
DOI:10.1149/04514.0015ecst