Formation of Macropore and Three-Dimensional Nanorod Array in p-Type Silicon

We carried out a study on the change in pore wall thickness depending on the current density in p-type silicon. We attempted the formation of a uniform macropore or nanorod array with a high aspect ratio in p-type silicon by electrochemical etching through the optimization of the hydrogen fluoride (HF)/organic electrolyte composition and the design of the mask pattern. The electrochemical etching of p-type silicon in the $\text{HF}: \text{dimethylsulfoxide (DMSO)}: \text{deionized (DI) water}= 1:5:5$ electrolyte can control the velocity of a reaction between an electrolyte and a hole necessary for the electrochemical etching of silicon through the mixing of the protic property of DI water and the aprotic property of DMSO. In this study, we fabricated a p-type silicon nanorod array of three-dimensional structures with an approximately 350 nm diameter from macroporous Si by applying two-step currents (40 mA, 200 s + 38 mA, 1600 s) to a 1.8 cm 2 circular area using an optimized $\text{HF}: \text{DMSO}: \text{DI water}= 1:5:5$ electrolyte composition.