Ternary charge transfer complexes. II. Complexes with Group III and IV elements in the anion

Ternary charge transfer complexes. II. Complexes with Group III and IV elements in the anion

Intensely colored charge transfer complexes are formed from NOMX 4 (M = B,Al,Ga,Tl; X = Cl,F) and benzene or methyl substituted benzenes. (NO) 2 MX 6 (M = Si,Ge,Sn,Tl; X = Cl,F) also form complexes with methyl substituted benzenes. Magnetic resonance and optical spectroscopic parameters are presente...

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Veröffentlicht in:Canadian journal of chemistry 1986-02, Vol.64 (2), p.265-269
Hauptverfasser: Brownstein, Sydney, Morrison, Anne, Tan, Liang K
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Miscellaneous
Preparations and properties
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Zusammenfassung:Intensely colored charge transfer complexes are formed from NOMX 4 (M = B,Al,Ga,Tl; X = Cl,F) and benzene or methyl substituted benzenes. (NO) 2 MX 6 (M = Si,Ge,Sn,Tl; X = Cl,F) also form complexes with methyl substituted benzenes. Magnetic resonance and optical spectroscopic parameters are presented. NOMX 4 forms stronger complexes than (NO) 2 MX 6 and complexes containing fluorine are stronger than those with chlorine.
ISSN:0008-4042
1480-3291
DOI:10.1139/v86-045