Étude, par spectroscopie de vibration, de l'autoprotolyse de l'acide nitrique absolu. Nouvelle interprétation
The ir and Raman spectra of solid and liquid anhydrous HNO 3 have been investigated for the purpose of solving the self-dissociation problem. Identified species are: the oligomer (HNO 3 ), (chains), NO 2 + and (NO 3 •3HNO 3 ) − ions, two monohydrate forms: the ionic pair H 2 OH+… ONO 2 − and the mol...
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| Veröffentlicht in: | Canadian journal of chemistry 1985-07, Vol.63 (7), p.1492-1501 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The ir and Raman spectra of solid and liquid anhydrous HNO
3
have been investigated for the purpose of solving the self-dissociation problem. Identified species are: the oligomer (HNO
3
), (chains), NO
2
+
and (NO
3
•3HNO
3
)
−
ions, two monohydrate forms: the ionic pair H
2
OH+… ONO
2
−
and the molecular association H
2
O … HONO
2
, and, finally, some free H
3
O
+
ions. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v85-256 |