Arrhenius Parameter for Some Gas-phase Cycloaddition Reactions of Singlet Molecular Oxygen
Rate constants have been determined for several reactions of O 2 ( 1 Δ g ) in the gas phase, at temperatures between 300 and 550 °K. The following values were obtained when the data was fitted to the Arrhenius equation: A charge-transfer interaction in the transition-state is invoked to account for...
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| Veröffentlicht in: | Canadian journal of chemistry 1974-10, Vol.52 (20), p.3544-3548 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Rate constants have been determined for several reactions of O
2
(
1
Δ
g
) in the gas phase, at temperatures between 300 and 550 °K. The following values were obtained when the data was fitted to the Arrhenius equation:
A charge-transfer interaction in the transition-state is invoked to account for the data available for such reactions. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v74-526 |