The Formation of Alkenes by the Thermal Elimination Reaction of N-Methyl-4-Alkoxypyridinium Iodides. I. Scope of the Reaction

Twenty-one 4-alkoxypyridines and their corresponding N-methyl-4-alkoxypyridinium iodides have been prepared and the latter pyrolyzed at temperatures ranging from room temperature to 185° to give the olefins derived from the alkyl moiety in high yields.

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Veröffentlicht in:Canadian journal of chemistry 1972-04, Vol.50 (8), p.1181-1187
Hauptverfasser: Schmid, George H, Wolkoff, Aaron W
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:Twenty-one 4-alkoxypyridines and their corresponding N-methyl-4-alkoxypyridinium iodides have been prepared and the latter pyrolyzed at temperatures ranging from room temperature to 185° to give the olefins derived from the alkyl moiety in high yields.
ISSN:0008-4042
1480-3291
DOI:10.1139/v72-185