Selective reduction of esters with sodium trimethoxyborohydride
The rate of reduction of representative methyl esters with sodium trimethoxyborohydride decreases in the order primary > secondary > tertiary. Sodium trimethoxyborohydride reduces with 100% selectivity the secondary ester group in the alicyclic diester-acid 2 c.
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| Veröffentlicht in: | Canadian journal of chemistry 1969-06, Vol.47 (11), p.2099-2102 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The rate of reduction of representative methyl esters with sodium trimethoxyborohydride decreases in the order primary > secondary > tertiary. Sodium trimethoxyborohydride reduces with 100% selectivity the secondary ester group in the alicyclic diester-acid
2
c. |
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| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v69-338 |