Abstraction of hydrogen from hydrogen sulfide by methyl radicals

Abstraction of hydrogen from hydrogen sulfide by methyl radicals

The methyl radical attack on H 2 S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF 3 radicals may react with H 2 S faster than CH 3 radicals.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Canadian journal of chemistry 1969-02, Vol.47 (4), p.689-690
Hauptverfasser: Gray, Peter, Herod, A. A, Leyshon, L. J
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The methyl radical attack on H 2 S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF 3 radicals may react with H 2 S faster than CH 3 radicals.
ISSN:0008-4042
1480-3291
DOI:10.1139/v69-106