Synthesis of 2,6-Di-O-methyl-D-mannose

Synthesis of 2,6-Di-O-methyl-D-mannose

2,6-Di-O-methyl- D -mannose was synthesized using the following sequence of reactions: 1,3,4,6-tetra-O-acetyl-2-O-methyl-β- D -mannopyranose → methyl 2-O-methyl-α- D -mannopyranoside → methyl 2-O-methyl-6-O-trityl-α- D -mannopyranoside → methyl 3,4-di-O-acetyl-2-O-methyl-6-O-trityl-α- D -mannopyrano...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Canadian journal of chemistry 1969-01, Vol.47 (1), p.31-33
Hauptverfasser: Perry, M. B, Webb, Ann C
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:2,6-Di-O-methyl- D -mannose was synthesized using the following sequence of reactions: 1,3,4,6-tetra-O-acetyl-2-O-methyl-β- D -mannopyranose → methyl 2-O-methyl-α- D -mannopyranoside → methyl 2-O-methyl-6-O-trityl-α- D -mannopyranoside → methyl 3,4-di-O-acetyl-2-O-methyl-6-O-trityl-α- D -mannopyranoside → methyl 3,4-di-O-acetyl-2-O-methyl-α- D -mannopyranoside → methyl 3,4-di-O-acetyl-2,6-di-O-methyl-α- D -mannopyranoside → 2,6-di-O-methyl- D -mannose. The preparation and properties of derivatives of the 2,6-di-O-methyl- D -mannose are recorded.
ISSN:0008-4042
1480-3291
DOI:10.1139/v69-003