PHOTOREARRANGEMENT OF 2,3-DIMETHYL-4,5-DIHYDROFURAN AND 2-METHYL-4,5-DIHYDROFURAN

PHOTOREARRANGEMENT OF 2,3-DIMETHYL-4,5-DIHYDROFURAN AND 2-METHYL-4,5-DIHYDROFURAN

Irradiation of an ether solution of the title compounds with a medium-pressure mercury are gave in each case a rearrangement reaction, with formation of an acetyl cyclopropane isomer as the major product. This reaction is similar to that induced thermally at 450°.

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Veröffentlicht in:Canadian journal of chemistry 1965-05, Vol.43 (5), p.1417-1418
Hauptverfasser: McGreer, Donald E, Vinje, Magnus G, McDaniel, Robert S
Format: Artikel
Sprache:eng
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Zusammenfassung:Irradiation of an ether solution of the title compounds with a medium-pressure mercury are gave in each case a rearrangement reaction, with formation of an acetyl cyclopropane isomer as the major product. This reaction is similar to that induced thermally at 450°.
ISSN:0008-4042
1480-3291
DOI:10.1139/v65-191