SULFONIUM SALT SOLVOLYSIS: PART V. MODEL SYSTEMS FOR BIOLOGICAL TRANSMETHYLATION
The rates of solvolysis of a series of sulfonium salts which may be considered as models for the biologically important sulfonium salt, S-adenosylmethionine, are discussed in terms of a possible anchimeric role of the carboxyl group of methionine in transmethylation reactions.
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| Veröffentlicht in: | Canadian journal of chemistry 1965-01, Vol.43 (1), p.57-63 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The rates of solvolysis of a series of sulfonium salts which may be considered as models for the biologically important sulfonium salt, S-adenosylmethionine, are discussed in terms of a possible anchimeric role of the carboxyl group of methionine in transmethylation reactions. |
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| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v65-008 |