ADDITION OF n-BUTYL MERCAPTAN TO 1-PENTENE ON IRRADIATION WITH X-RAYS OR GAMMA RAYS: I. 140 KVP. X-RAYS

ADDITION OF n-BUTYL MERCAPTAN TO 1-PENTENE ON IRRADIATION WITH X-RAYS OR GAMMA RAYS: I. 140 KVP. X-RAYS

n-Butyl mercaptan reacts with 1-pentene when irradiated with X-rays. The dependence of reaction rate upon concentration of mercaptan and pentene has been studied as well as the dependence on dose rate. A comparison with the photoinitiated reaction is made.

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Veröffentlicht in:Canadian journal of chemistry 1957-12, Vol.35 (12), p.1384-1396
Hauptverfasser: Fontijn, A, Spinks, J. W. T
Format: Artikel
Sprache:eng
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Zusammenfassung:n-Butyl mercaptan reacts with 1-pentene when irradiated with X-rays. The dependence of reaction rate upon concentration of mercaptan and pentene has been studied as well as the dependence on dose rate. A comparison with the photoinitiated reaction is made.
ISSN:0008-4042
1480-3291
DOI:10.1139/v57-183