ORGANIC DEUTERIUM COMPOUNDS: XIII. THE MECHANISM OF THE NEF EACTION SYNTHESIS OF ETHANAL-1-d
The mechanism of the Nef reaction was investigated with nitroethane-1,1-d 2 . The isolation of 95 mole % ethanal-1-d in 70% yield renders a mechanism proposed by Mahler untenable, but supports others submitted by van Tamelen and Thiede and by Nametkin.
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| Veröffentlicht in: | Canadian journal of chemistry 1955-02, Vol.33 (2), p.400-404 |
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| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The mechanism of the Nef reaction was investigated with nitroethane-1,1-d
2
. The isolation of 95 mole % ethanal-1-d in 70% yield renders a mechanism proposed by Mahler untenable, but supports others submitted by van Tamelen and Thiede and by Nametkin. |
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| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v55-047 |