Synthesizing methanol from nitrogen-ballasted syngas

The possibility of the effective catalytic synthesis of methanol from nitrogen-ballasted syngas was studied. Syngas was obtained during the operation of power machines such as diesel engines or gas turbines. The dependences of CO and CO 2 conversion per cycle, the quality of methanol, et cetera on t...

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Veröffentlicht in:Catalysis in industry 2010-12, Vol.2 (4), p.368-373
Hauptverfasser: Lishchiner, I. I., Malova, O. V., Tarasov, A. L., Maslennikov, V. M., Vyskubenko, Yu. A., Tolchinskii, L. S., Dolinskii, Yu. L.
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Sprache:eng
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Zusammenfassung:The possibility of the effective catalytic synthesis of methanol from nitrogen-ballasted syngas was studied. Syngas was obtained during the operation of power machines such as diesel engines or gas turbines. The dependences of CO and CO 2 conversion per cycle, the quality of methanol, et cetera on the composition of syngas are characterized. The kinetic dependences of methanol synthesis on G-79-7GL catalyst (Zud Chemie) are described. For nitrogen-ballasted syngas, the dependences of the CO and CO 2 conversion and the output and quality of methanol on the reaction conditions (pressure, temperature, and gas mixture feed rate) are the same as for nitrogen-free syngas, though the CO conversion declined considerably when the concentration of ballast nitrogen was increased. These studies served as the basis for the creation of energy-independent units for processing hydrocarbon gases into methanol and motor fuels.
ISSN:2070-0504
2070-0555
DOI:10.1134/S2070050410040112