Catalytic nitrobenzene hydrogenation in supercritical carbon dioxide

Catalytic nitrobenzene hydrogenation in supercritical carbon dioxide

The results of catalytic hydrogenation of nitrobenzene on Pd-containing catalysts in different media, such as supercritical carbon dioxide (SC-CO 2 ) and isopropyl alcohol, as well as without any solvent are presented. A significant increase in the reaction rate of nitrobenzene hydrogenation was obs...

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Veröffentlicht in:Russian journal of physical chemistry. B 2014-12, Vol.8 (7), p.958-962
Hauptverfasser: Doluda, V. Yu, Tereshchenkov, A. Yu, Demidenko, G. N., Lakina, N. V., Sul’man, E. M., Sul’man, M. G., Matveeva, V. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Physical Chemistry
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Zusammenfassung:The results of catalytic hydrogenation of nitrobenzene on Pd-containing catalysts in different media, such as supercritical carbon dioxide (SC-CO 2 ) and isopropyl alcohol, as well as without any solvent are presented. A significant increase in the reaction rate of nitrobenzene hydrogenation was observed in SC-CO 2 . The catalytic activity decreased with decreasing metal content in the catalyst.
ISSN:1990-7931
1990-7923
DOI:10.1134/S1990793114070070