Chirooptical effects in dilute solutions of gelators

The chirooptical properties of a number of compounds in a variety of achiral solvents are studied. The results are interpreted within the framework of the standard model of chiral molecules. It is demonstrated that, with increasing concentration, chiral aggregates emerge, up to the formation of a ma...

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Veröffentlicht in:	Russian journal of physical chemistry. B 2012-05, Vol.6 (3), p.341-347
Hauptverfasser:	Stovbun, S. V., Zanin, A. M., Skorobogat’ko, D. S., Skoblin, A. A., Litvin, Ya. A., Mikhailov, A. I., Krutius, O. N., Kostyanovskii, R. G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Physical Chemistry Structure of Chemical Compounds. Spectroscopy
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The chirooptical properties of a number of compounds in a variety of achiral solvents are studied. The results are interpreted within the framework of the standard model of chiral molecules. It is demonstrated that, with increasing concentration, chiral aggregates emerge, up to the formation of a macrophase (strings), which radically changes the chirooptical characteristics of the solution.
ISSN:	1990-7931 1990-7923
DOI:	10.1134/S1990793112050107