Three-dimensional simulation of free-radical block polymerization of diallyl isophthalate by the Monte Carlo method

Three-dimensional simulation of free-radical block polymerization of diallyl isophthalate by the Monte Carlo method

A model of the three-dimensional free-radical block polymerization of diallyl isophthalate to a limiting degree of conversion is developed. The core of the model is a reactor built on a cubic lattice of size 100 × 100 × 100. The influence of chain transfer to the monomer and of diffusion effect on t...

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Veröffentlicht in:Russian journal of physical chemistry. B 2011-10, Vol.5 (5), p.861-869
Hauptverfasser: Shakir’yanov, E. D., Ismailov, R. R., Usmanov, S. M., Sivergin, Yu. M.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Physics of Polymer Materials
Chemistry
Chemistry and Materials Science
Physical Chemistry
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Zusammenfassung:A model of the three-dimensional free-radical block polymerization of diallyl isophthalate to a limiting degree of conversion is developed. The core of the model is a reactor built on a cubic lattice of size 100 × 100 × 100. The influence of chain transfer to the monomer and of diffusion effect on the kinetic characteristics of the polymerization process is examined.
ISSN:1990-7931
1990-7923
DOI:10.1134/S1990793111090107