Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)

The article presents the results of a study of new ceramic materials formed in the MeO–Cr 2 O 3 –Bi 2 O 3 (Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges f...

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Veröffentlicht in:Glass physics and chemistry 2021-11, Vol.47 (6), p.684-691
Hauptverfasser: Ershov, D. S., Besprozvannykh, N. V., Sinel’shchikova, O. Yu
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Besprozvannykh, N. V.
Sinel’shchikova, O. Yu
description The article presents the results of a study of new ceramic materials formed in the MeO–Cr 2 O 3 –Bi 2 O 3 (Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges from 3.82 × 10 –4 up to 1.0 × 10 –2 S/cm, and the activation energy of conduction E a lies in the range from 0.564 to 0.842 eV. The charge transfer in the obtained solid electrolytes is of a mixed nature; however, a significant part (≥90%) is occupied by the oxygen-ion component.
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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Glass
Materials Science
Natural Materials
Physical Chemistry
title Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)
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