Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)
The article presents the results of a study of new ceramic materials formed in the MeO–Cr 2 O 3 –Bi 2 O 3 (Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges f...
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Veröffentlicht in: | Glass physics and chemistry 2021-11, Vol.47 (6), p.684-691 |
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container_title | Glass physics and chemistry |
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creator | Ershov, D. S. Besprozvannykh, N. V. Sinel’shchikova, O. Yu |
description | The article presents the results of a study of new ceramic materials formed in the MeO–Cr
2
O
3
–Bi
2
O
3
(Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges from 3.82 × 10
–4
up to 1.0 × 10
–2
S/cm, and the activation energy of conduction
E
a
lies in the range from 0.564 to 0.842 eV. The charge transfer in the obtained solid electrolytes is of a mixed nature; however, a significant part (≥90%) is occupied by the oxygen-ion component. |
doi_str_mv | 10.1134/S1087659621060079 |
format | Article |
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2
O
3
–Bi
2
O
3
(Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges from 3.82 × 10
–4
up to 1.0 × 10
–2
S/cm, and the activation energy of conduction
E
a
lies in the range from 0.564 to 0.842 eV. The charge transfer in the obtained solid electrolytes is of a mixed nature; however, a significant part (≥90%) is occupied by the oxygen-ion component.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1134/S1087659621060079</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Glass ; Materials Science ; Natural Materials ; Physical Chemistry</subject><ispartof>Glass physics and chemistry, 2021-11, Vol.47 (6), p.684-691</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1087-6596, Glass Physics and Chemistry, 2021, Vol. 47, No. 6, pp. 684–691. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Fizika i Khimiya Stekla.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c218t-ecdff5c84859daac081789723c830c6fb713e12fe68302855b33a5975ce193063</citedby><cites>FETCH-LOGICAL-c218t-ecdff5c84859daac081789723c830c6fb713e12fe68302855b33a5975ce193063</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1087659621060079$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1087659621060079$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Ershov, D. S.</creatorcontrib><creatorcontrib>Besprozvannykh, N. V.</creatorcontrib><creatorcontrib>Sinel’shchikova, O. Yu</creatorcontrib><title>Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)</title><title>Glass physics and chemistry</title><addtitle>Glass Phys Chem</addtitle><description>The article presents the results of a study of new ceramic materials formed in the MeO–Cr
2
O
3
–Bi
2
O
3
(Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges from 3.82 × 10
–4
up to 1.0 × 10
–2
S/cm, and the activation energy of conduction
E
a
lies in the range from 0.564 to 0.842 eV. The charge transfer in the obtained solid electrolytes is of a mixed nature; however, a significant part (≥90%) is occupied by the oxygen-ion component.</description><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Glass</subject><subject>Materials Science</subject><subject>Natural Materials</subject><subject>Physical Chemistry</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9ULFOwzAQtRBIlMIHsHkEiYAdN7EzMNCIAlKrIlIktsh1LsRVk1S-dOjGDzDxh3wJDrAhsdy7e-_e6fQIOeXsknMxuso4UzKOkjjkLGZMJntkwGOmAsHFy77vvRz0-iE5QlwxxhIpRwPynu2argK0SHVT0CdA0M5UtC2pp-ljpRHopHW17mzb9HTWrm3R123PYE-NLdbbrqJp5Vq_CEht821fOLtZA8122EGNdAbzz7eP1IVz4XFsPdKzGdBrmrkLmurzY3JQ6jXCyS8OyfPkdpHeB9P53UN6Mw1MyFUXgCnKMjJqpKKk0NowxaVKZCiMEszE5VJyATwsIfZzqKJoKYSOEhkZ4IlgsRgS_nPXuBbRQZlvnK212-Wc5X2e-Z88vSf88aDfbV7B5at26xr_5j-mL1rNd-0</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Ershov, D. S.</creator><creator>Besprozvannykh, N. V.</creator><creator>Sinel’shchikova, O. Yu</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211101</creationdate><title>Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)</title><author>Ershov, D. S. ; Besprozvannykh, N. V. ; Sinel’shchikova, O. Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c218t-ecdff5c84859daac081789723c830c6fb713e12fe68302855b33a5975ce193063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Glass</topic><topic>Materials Science</topic><topic>Natural Materials</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ershov, D. S.</creatorcontrib><creatorcontrib>Besprozvannykh, N. V.</creatorcontrib><creatorcontrib>Sinel’shchikova, O. Yu</creatorcontrib><collection>CrossRef</collection><jtitle>Glass physics and chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ershov, D. S.</au><au>Besprozvannykh, N. V.</au><au>Sinel’shchikova, O. Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca)</atitle><jtitle>Glass physics and chemistry</jtitle><stitle>Glass Phys Chem</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>47</volume><issue>6</issue><spage>684</spage><epage>691</epage><pages>684-691</pages><issn>1087-6596</issn><eissn>1608-313X</eissn><abstract>The article presents the results of a study of new ceramic materials formed in the MeO–Cr
2
O
3
–Bi
2
O
3
(Me = Sr, Ca) system in the solid-phase synthesis and pyrolysis of organo-salt compositions using mannitol as fuel. The total electrical conductivity of the synthesized samples at 600°C ranges from 3.82 × 10
–4
up to 1.0 × 10
–2
S/cm, and the activation energy of conduction
E
a
lies in the range from 0.564 to 0.842 eV. The charge transfer in the obtained solid electrolytes is of a mixed nature; however, a significant part (≥90%) is occupied by the oxygen-ion component.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1087659621060079</doi><tpages>8</tpages></addata></record> |
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language | eng |
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source | SpringerLink Journals |
subjects | Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Glass Materials Science Natural Materials Physical Chemistry |
title | Synthesis and Research of the Phase Formation of Solid Solutions of Bismuth Chromates in the Triple Systems MeO–Cr2O3–Bi2O3 (Me = Sr, Ca) |
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