Spirocyclic 2,5-dihydro-1H-imidazole 1-oxyl radicals with a mesogenic substituent on C4. Synthesis and crystal structure

Spirocyclic 2,5-dihydro-1H-imidazole 1-oxyl radicals with a mesogenic substituent on C4. Synthesis and crystal structure

Stable spirocyclic 2,5-dihydro-1 H -imidazole 1-oxyl radicals containing a mesogenic fragment were synthesized on the basis of 1-[4-hydroxy(alkoxy)phenyl]-2-hydroxyamino-2-methylpropan-1-ones. The crystalline structure of two aminoxyl radicals was determined by X-ray analysis.

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Veröffentlicht in:Russian journal of organic chemistry 2014, Vol.50 (1), p.72-77
Hauptverfasser: Zaytseva, E. V., Gatilov, Yu. V., Amitina, S. A., Tamura, R., Grigor’ev, I. A., Mazhukin, D. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Zusammenfassung:Stable spirocyclic 2,5-dihydro-1 H -imidazole 1-oxyl radicals containing a mesogenic fragment were synthesized on the basis of 1-[4-hydroxy(alkoxy)phenyl]-2-hydroxyamino-2-methylpropan-1-ones. The crystalline structure of two aminoxyl radicals was determined by X-ray analysis.
ISSN:1070-4280
1608-3393
DOI:10.1134/S107042801401014X